Skip to main content

Ring opening Polymerisation.

Ring opening Polymerisation

Ring opening Polymerisation have some features similar with addition and condensation polymerisation mechanism, they show at least one important different features from each of these polymerisation. In ring opening polymerisation the small molecules does not split up, while in condensation polymers it does. This Polymerisation is different from olefins polymerisation , in the sense that the driving force for this polymerisation is not derived from the loss of unsaturation of monomers.
This polymerisation generally gives linear compounds. These have generally same composition as that of the monomers. Not all Cyclic compounds undergo ring opening polymerisation. The general ring opening polymerisation is given by equation below.
Ring opening polymerisation.
Where X is heteroatom or a group.
Some common example of ring opening polymerisation reaction.
Examples of ring opening polymerisation.

Comments

Popular posts from this blog

Difference between organic and inorganic polymers.

Difference between organic and inorganic polymers. Definition Organic polymers are the polymers that essentially contain carbon atom in the backbone. Inorganic polymers are the polymers that have no carbon atom in the backbone. Structure Most organic polymers have simple structures. Almost all inorganic polymers are highly branched and have complex structures. Electrical Conductivity In most of the aqueous solutions, organic polymers are typically poor conductors of electricity and heat. Inorganic polymers in aqueous solutions are good conductors of electricity, this is because they have high ability to ionise and this makes them better conductors. Flammability Organic polymers are flammable whereas inorganic polymers are nonflammable. Effect on nature Organic polymers are environmental friendly as these are biodegradable. Inorganic polymers are not environmental friendly as these are non biodegradable. Examples Organic polymers include polysaccharide...

Determination of molecular weight of polymers by viscosity method.

Determination of molecular weight of polymers by viscosity method. It is a simple method for determining the molecular weight of polymers. Addition of polymers in the solvent increases the viscosity of the solvent, due to introduction of inhomogeneities by the polymers. If η₀ is the viscosity of the solvent and η is the viscosity of the solution at the same temperature, then the relative viscosity is given by Relative viscosity. Specific viscosity:  It is defined as the relative increase in viscosity and is given as Specific viscosity. Reduced viscosity: It is defined as the relative increase in viscosity per unit concentration (C) of polymer and is given as Reduced viscosity. Intrinsic viscosity: The reduced viscosity is dependent on concentration (C). If a graph is plotted between  reduced viscosity vs concentration then the extraplotation value when C=0 is called intrinsic viscosity. Intrinsic viscosity. Graph of reduced vi...

Monomers.

Monomers. A monomer is a molecule that can be reacted together with other monomer molecules to form a larger polymer chain. Some monomers are given below with their polymers . Tetrafluoroethene ; Tetrafluoroethene is the monomer of Teflon . Teflon and its monomer. Acrylonitrile (vinyl cyanide); Acrylonitrile is the monomer of Polyacrylonitrile . Polyacrylonitrile and its monomer. Isoprene; Isoprene is the monomer of Polyisoprene (natural rubber). Polyisoprene and its monomer. Chloroprene; Chloroprene is the monomer of Neoprene . Neoprene and its monomer. Vinyl chloride; Vinyl chloride is the monomer of Poly(vinyl chloride) . Polyvinyl chloride and its monomer. Vinyl acetate; Vinyl acetate is the monomer of Poly(vinyl acetate). Poly(vinyl acetate) and its monomer. Propylene; Propylene is the monomer of Polypropylene . Polypropylene and its monomer. Styrene; Styrene is the monomer of Polystyrene . Polystyrene and i...